Consider the reaction at 298 K: 2H2S(g)+SO2(g)→3S(s,rhombic)+2H2O(g) ΔG∘rxn=−102kJ?

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Calculate ΔGrxn under these conditions:

PH2S= 2.01 atm

PSO2= 1.46 atm

PH2O=0.0126 atm

Is the reaction more or less spontaneous under these conditions than under standard conditions?

1 Answer

  • ΔGrxn = ΔG∘rxn + RT ln PH2O^2 / PH2S^2 PSO2

    ΔGrxn = -102 kJ + (8.314 J/molK) (298K) ln (0.0126)^2 / (2.01)^2(1.46) = -128 kJ

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