Determine the value of rate constant for the reaction based on the following pressures?

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Cyclobutane decomposes to ethylene according to the equation:

C4Hg(g) → 2C2H4(g)

Determine the value of rate constant for the reaction based on the following pressures, which were recorded when the reaction was carried out at 430 degree C in a constant-Volume Vessel.

Time (s) mmHg

0 400

2000 316

4000 248

6000 196

8000 155

10000 122

1 Answer

  • Conc = initial conc * e^(-kt)

    Rearrange and substitute:

    ln(316/400) = -k (2000s)

    k=.000118 s^-1

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